Journal
MACROMOLECULAR MATERIALS AND ENGINEERING
Volume 298, Issue 1, Pages 53-66Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201100390
Keywords
adhesives; crosslinking; miniemulsion polymerization; Monte Carlo simulation; structure-property relations
Funding
- EU
- Diputacion Foral de Gipuzkoa, Basque Government [GV IT373-10, S-PE10UN25]
- Ministerio de Ciencia e Innovacion (MICINN) [CTQ2011-25572]
- Basque Government (Ikertzaileak Prestatzeko eta Hobetzeko Beken Programak'')
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The effects of the CTA concentration on polymerization kinetics, polymer microstructure, particle morphology, and adhesive performance of waterborne hybrid PSAs prepared by simultaneous free-radical and addition miniemulsion polymerizations are studied. The development of the microstructure is shown to differ from waterborne acrylic PSAs obtained by free-radical polymerization because of the contribution of the addition reaction, which in turn causes marked differences in the adhesive performance of the final films. A computer simulation is developed to obtain detailed information about the microstructure of PU/acrylic hybrids and to correlate the microstructure with the final adhesive properties.
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