4.5 Article

A Completely Biodegradable Poly[(L-lactide)-co-(ε-caprolactone)] Elastomer Reinforced by in situ Poly(glycolic acid) Fibrillation: Manufacturing and Shape-Memory Effects

Journal

MACROMOLECULAR MATERIALS AND ENGINEERING
Volume 295, Issue 4, Pages 381-385

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.200900251

Keywords

biodegradable; in situ fibrillations; microfibers; morphology; shape-memory polymers

Funding

  1. Chinese Academy of Sciences
  2. Science and Technology Department of Zhejiang Province, China [2008C11126]

Ask authors/readers for more resources

A new completely biodegradable shape-memory elastomer consisting of PLLCA reinforced by in situ PGA fibrillation is described. The manufacturing processes and shape-memory effects of the composites are discussed. DMA results reveal a strong interface interaction between in situ PGA fibrillation and PLLCA. Compared with the SMP-based composites that are commonly used, the shape-memory test shows that in situ PGA fibrillation can improve the recovery properties of PLLCA; in fact, the shape-recovery rate increases from 80.5 to 93.2%.

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