Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 215, Issue 8, Pages 699-704Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201300762
Keywords
anionic polymerization; atom transfer radical polymerization; ferrocenes; metallo polymers; redox-responsive materials
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Funding
- Landesoffensive zur Entwicklung Wissenschaftlich-okonomischer Exzellenz (LOEWE Soft Control)
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The synthesis of metal-containing polymers and block copolymers has led to a rapidly expanding field of research interest for manifold potential applications. Within this contribution, some recent advances in the field of side-chain ferrocene-containing polymers focusing on poly(vinylferrocene) and poly(ferrocenyl methacrylates) are presented. The synthetic developments shown focus on living and controlled polymerizations, as well as surface-initiated polymerization strategies. First attempts and recent developments for these novel redox-responsive materials toward feasible applications are addressed.
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