Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 215, Issue 8, Pages 742-752Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201300729
Keywords
azo-polymers; nematics; polysiloxanes; self-assembly
Categories
Funding
- Hungarian Research Fund [OTKA-K 81250, OTKA-NN 110672]
- Czech-Hungarian bilateral project (ASCR-HAS) [SNK-70/2013, HU/2013/08]
- specific university research (MSMT) [20/2013]
- [ASCR M100101204]
- [CSF 13-14133S]
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A new azobenzene-group-containing monomer and several respective functional side-chain polymers grafted on a methylhydrosiloxane backbone (with two different degrees of polymerization; with and without the addition of a photoreactive benzophenone derivative) are designed, synthesized, and characterized. The resulting materials clearly show self-assembly behavior and possess a nematic liquid-crystal phase over a broad temperature range, which extends below 0 degrees C. The optical properties of these new photochromic liquid-crystalline materials are determined from the absorbance spectra of oriented samples and by photoinduced birefringence studies. The results indicate a considerable dichroism of the side-chain liquid-crystalline polymers (SCLCPs), and hence demonstrate their potential applicability for optical storage.
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