Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 213, Issue 5, Pages 539-548Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201100571
Keywords
polysaccharide; cellulose; amino cellulose sulfate; polyelectrolyte; titration; ampholyte; bioactivity
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Funding
- European Community [214015]
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The physicochemical behavior with emphasis on the charging behavior of 6-deoxy-6-(2-(bis(2-aminoethyl)aminoethyl-amino) cellulose sulfate (BAECS) with degree of substitution (DS) of 1.31 (sulfate moieties) and 0.71 (amino moieties) and of 6-deoxy-6-(2-aminoethyl) cellulose sulfate (AECS, DSSulf = 1.41, DSDAE = 0.85, DSTosyl = 0.09) is studied by using several types of titrations. The amounts of protonated amino groups determined by conductometric titration are 4.02 and 2.53 mmol g-1 for BAECS and AECS, respectively. The amino groups are fully deprotonated at pH greater than or similar to 11, whereas the sulfate moieties determined by polyelectrolyte titration are fully dissociated at this pH value. Furthermore, studies on the antimicrobial and antithrombogenetic efficiencies of the samples are carried out.
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