Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 213, Issue 15, Pages 1590-1595Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201200099
Keywords
fluorescence; monodispersed microspheres; polyphosphazenes; self-assembly; ultraviolet-visible absorption
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Funding
- foundation of the Key Laboratory for Advanced Materials Processing Technology, Ministry of Education, P. R. China [2010003]
- NSFC [61006002]
- Shanghai Science & Technology Committee [10ZR1416100]
- Shanghai Leading Academic Discipline Project [B202]
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More and more attention is focused on monodispersed, functionalized microspheres with tunable size. In this article, a facile, efficient self-assembly process is successfully developed to fabricate novel monodispersed microspheres based on hybrid polyphosphazene, and the size of the microspheres is proven to be easily tailorable. The polymer exhibits excellent thermal and intrinsically fluorescent properties which make up the deficiency of generally fluorescent material prepared by embedding with quantum dots or dyes in some special domains. In addition, a broad ultraviolet-visible absorption is observed from 300 to 450 nm, and all these superior properties may result in potential applications in ablation-resistant materials, solar energy photoelectric materials and biomaterials.
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