Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 212, Issue 3, Pages 272-277Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201000439
Keywords
conjugated polymers; FT-IR; NMR; polyphosphazenes; synthesis
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Funding
- National Natural Science Foundation of China [50703034]
- Zhejiang Provincial Natural Science Foundation of China [Y4100146]
- National Natural Science Foundation of China for Distinguished Young Scholars [50625309]
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A versatile approach based on click chemistry to synthesize polyphosphazene glycopolymers is presented. The glucose-substituted polyphosphazene was synthesized by nucleophilic substitution of poly(dichlorophosphazene) with propargylamine and the subsequent azide/alkyne click reaction of poly[di(propargyl-amine)phosphazene] (PDPAP) with azidosugar. The relative proportion of the glucose substituent can be easily controlled over a broad range by varying the amount of azidoglucose used in the azide/alkyne click reaction.
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