Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 212, Issue 2, Pages 134-149Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201000472
Keywords
ATRP; graft copolymers; Li+ ion conductivity; mechanical properties; porous morphology
Categories
Funding
- Department of Science and Technology, New Delhi [SR/S1/PC/26/2009]
- CSIR, New Delhi
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PnBMA is grafted on PVDF using ATRP in NMP solution at 90 degrees C and characterized by means of 1D and 2D NMR. F-19 NMR spectra clearly reveal that the attack occurs on the head-head >CF2 groups. Cast PB films show a honeycomb-patterned porous microstructure, and the breath-figure model is used to explain pore formation. FT-IR spectra suggest a supramolecular interaction between >C=O groups of PnBMA and >CF2 groups of PVDF. Storage modulus, loss modulus and stress at break decrease with graft conversion, but the strain at break increases significantly. The toughness of the copolymers also increases dramatically (882%). The porous materials can be applied as solid-state electrolytes (Li+-doped) with good ionic conductivity (10(-5) S.cm(-1)).
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