4.4 Article

Facile Synthesis of Nanoporous Hydroquinone/Catechol Formaldehyde Resins and their Highly Selective, Efficient and Regenerate Reactive Adsorption for Gold Ions

Journal

MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 211, Issue 8, Pages 845-853

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200900534

Keywords

hypercrosslinked; porous polymers; reactive adsorption; synthesis

Funding

  1. National Nature Science Foundation of China [20633090, 50702072, 50823007]
  2. Shanghai Nanoscience Program [0852nm03900]

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We present a new type of nanoporous hydroquinone/catechol formaldehyde resin synthesized by a one-pot route, with a surface area of up to 1 112 m(2) . g(-1). The resins show highly efficient reactive adsorption for silver/gold (silver adsorbance up to 2.43 g . g(-1)) and excellent selectivity for gold (K-d is as high as 1 914090 mL . g(-1)). The first-used resins can be regenerated with NaHSO3, and the gold capacities of the recycled PCFR and PHFR reach 44 and 78% of their first loading capacities, respectively.

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