Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 210, Issue 22, Pages 1966-1972Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200900375
Keywords
catalysts; chain; growth; polymerization; polymerization (general); polythiophene; semiconducting polymers
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Funding
- NSF [DMR 0120967, DMR 0520567, DMR 0747489]
- ACS-PRF Type G
- Department of Energy Solar America Initiative
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0747489] Funding Source: National Science Foundation
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The effects of binding ligand variation on the externally initiated Ni catalyzed polymerization of P3HT were investigated using a novel methodology allowing facile screening of ligands. P3HT was synthesized with >80% initiator incorporation for both mono- and bidentate phosphine ligands. Variation of the initiating aryl group demonstrated vastly superior results for o-tolyl over p-tolyl substituents.
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