Journal
MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 209, Issue 9, Pages 930-937Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200700530
Keywords
amino acids; chiral recognition; norbornene; ROMP; stereo structures
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Amino acid-derived novel norbornene monomers were synthesized and polymerized with ruthenium catalysts. The polymerization rates were affected by the stereo structure of the monomers; exo,exo-NBL underwent ROMP faster to give the polymers in higher yields than the endo,exo-counterpart. The Grubbs 2nd generation catalyst was the most effective for the amino acid-based monomers. A polymer gel was synthesized by the copolymerization of exo,exo-NBL with 2.5 mol-% of bifunctional norbornene monomer. The gel adsorbed larger amounts of (R)-phenylalaninol and N-(benzyloxycarbonyl)alanine than those of the (S)-isomers.
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