Journal
MACROMOLECULAR BIOSCIENCE
Volume 9, Issue 4, Pages 376-382Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mabi.200800179
Keywords
cellulose; composites; gels; hydrogels; polysaccharides
Funding
- INOUE Research Foundation for Science, Tokyo
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Gels of three types of carrageenans (kappa-, iota- and lambda-), as well as their composite gels with cellulose, were prepared using an ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl), by a heating-cooling process. kappa-Carrageenan gave the formation of hard gel while the other two carrageenans gave the formation of softer gels with BMIMCl. The gels were characterized by X-ray diffraction (XRD), thermal analysis (TGA and DSC), scanning electron microscope (SEM) and compressive testing. The results indicated that, among the three types of carrageenans, kappa-and iota-carrageenans gave better miscible gels with BMIMCl, followed by lambda-carrageenan. on the other hand, lambda-carrageenan gave a better miscible composite gel with cellulose and BMIMCl, followed by iota- and kappa-carrageenans. The stress-strain curves indicated that the mechanical properties of the above gel systems on the compressive mode were much better than those of the hydrogels of kappa- and iota-carrageenans as well as the cellulose gel with BMIMCl.
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