Journal
MACROMOLECULAR BIOSCIENCE
Volume 9, Issue 2, Pages 157-161Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mabi.200800213
Keywords
hydrophilic polymers; living polymerization; polyamides; photochemistry; thermal properties
Funding
- Max Planck Society
- Fraunhofer Society
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The click modification of statistical poly[2-(isopropyl/3-butenyl)-2-oxazoline] copolymers with omega-functionalized thiols can be used to generate a toolbox of thermo-responsive polymers. The cloud points of the polymers can be finely tuned over a wide range as a function of composition and hydrophilicity of the side chain (hydrocarbon, alcohol, carboxylic acid, etc.). Glycopolymers can be prepared exhibiting predictable cloud points in the whole accessible temperature range for water.
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