Journal
LIQUID CRYSTALS
Volume 40, Issue 12, Pages 1619-1627Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/02678292.2012.755223
Keywords
5CB; anisotropic particles; rods; sphero-cylinders; self-assembly; anchoring; topological defects; elasticity; pair interaction
Funding
- National Science Foundation (NSF) [CMMI09-00468, MRSEC DMR11-20901]
- NSF Graduate Research Fellowship
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Microbullet particles, cylinders with one blunt end and one hemispherical end, offer a novel platform to study the effects of anisotropy and curvature on colloidal assembly in complex fluids. Here, we disperse microbullets in 4-cyano-4-pentylbiphenyl nematic liquid crystal (NLC) cells and form oriented elastic dipoles with a nematic point defect located near the curved end. This feature allows us to study particle interactions as a function of dipole alignment. By careful control of the surface anchoring at the particle surface and the confining boundaries, we study the interactions and assembly of microbullets under various conditions. When microbullets with homeotropic surface anchoring are dispersed in a planar cell, parallel dipoles form linear chains parallel to the director, similar to those observed with spherical particles in a planar cell, while antiparallel dipoles orient side-to-side. In a homeotropic cell, however, particles rotate to orient their long axis parallel to the director. When so aligned, parallel dipoles repel and form 2D ordered assemblies with hexagonal symmetry that ripen over time owing to attraction between antiparallel neighbours. Further, we show that the director orientation inside the cell can be altered by application of an electrical field, allowing us to flip microbullets to orient parallel to the director, an effect driven by an elastic torque. Finally, we detail the mechanisms that control the formation of 1D chains and hexagonal lattices with respect to the elasticity of the NLC.
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