Journal
LIQUID CRYSTALS
Volume 36, Issue 12, Pages 1355-1364Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/02678290903233991
Keywords
nematic; flexoelectricity; chirality
Funding
- Merck Chemicals Ltd
- EPSRC
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Measurements of the difference in flexoelectric coefficients (e1 - e3), using the sign convention as originally defined by Meyer, are reported from three experiments employing the flexoelectro-optic effect in different geometries. The uniform lying helix (ULH) structure is used to measure the tilt angle of the liquid crystal director with respect to the helix axis for an applied electric field, in order to infer a value for (e1 - e3). Alternatively, measurements of the flexoelectric difference can be made by considering the transmission through a device with an in-plane electric field aligned in either the Grandjean structure for highly chiral materials, or a twisted nematic (TN) structure for largely achiral materials. The results from the Grandjean and ULH structures show the equivalence of the measurement techniques with helix axis either perpendicular or parallel to the substrates. Further comparison of these results with the measurement from the achiral TN device shows that the difference in flexoelectric coefficients displays no dependence on chirality, demonstrating that flexoelectricity is purely associated with splay and bend director deformations, as expected from symmetry considerations.
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