Journal
APPLIED SURFACE SCIENCE
Volume 327, Issue -, Pages 77-85Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2014.11.103
Keywords
UiO-66; UiO-66-NH2; Selective adsorption
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Funding
- Natural Science Foundation of Anhui Province Altitude School of China [KJ2010A271]
- National Natural Science Foundation of China [51372062]
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Herein, two zirconium(IV)-based MOFs UiO-66 and UiO-66-NH2 had been successfully prepared by a facile solvothermal method and were characterized by X-ray diffraction (XRD), field emission transmission electron microscopy (FETEM), N-2 adsorption-desorption (BET), X-ray photoelectron spectroscopy (XPS), and zeta potential. They exhibit small size, large surface area, and can remove cationic dyes from aqueous solution more effectively than anionic dyes. This adsorption selectivity is due to the favorable electrostatic interactions between the adsorbents and cationic dyes. Furthermore, owing to the individual micropore structure of UiO-66-NH2 and its more negative zeta potential resulted from the charge balance for the protonation of -NH2, UiO-66-NH2 displays much higher adsorption capacity for cationic dyes and lower adsorption capacity for anionic dyes than UiO-66. (C) 2014 Elsevier B.V. All rights reserved.
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