Journal
LETTERS IN ORGANIC CHEMISTRY
Volume 5, Issue 6, Pages 473-477Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017808785740507
Keywords
Molybdenum(V) chloride; carbon-carbon bond formation; allylation; Lewis acid; glycosylation
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Funding
- CSIR, New Delhi
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The catalytic activity of Molybdenum(V) chloride as a Lewis acid in carbon-carbon bond formation reactions has been described. The reactions of various substrates viz. aldehydes, benzyl alcohols, glucals and aminals with carbon nucleophiles were studied in the presence of MoCl5 as a catalyst. Progress of all the reactions proceeded smoothly to furnish the corresponding products in good yields.
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