Journal
LANGMUIR
Volume 30, Issue 2, Pages 452-460Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la4032514
Keywords
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Funding
- U.K. Engineering and Physical Science Research Council (EPSRC) [EP/F032005/1]
- University of Vienna
- Challenging Engineering Programme of the EPSRC [EP/E007538/1]
- Engineering and Physical Sciences Research Council [EP/E007538/1, EP/J013390/1, EP/F032005/1] Funding Source: researchfish
- Grants-in-Aid for Scientific Research [24750139] Funding Source: KAKEN
- EPSRC [EP/E007538/1, EP/J013390/1, EP/F032005/1] Funding Source: UKRI
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Water-in-oil emulsions stabilized solely by bacterial cellulose nanofibers (BCNs), which were hydrophobized by esterification with organic acids of various chain lengths (acetic acid, C-2-; hexanoic acid, C-6-; dodecanoic acid, C-12-), were produced and characterized. When using freeze-dried C-6-BCN and C-12-BCN, only a maximum water volume fraction (phi(w)) of 60% could be stabilized, while no emulsion was obtained for C-2-BCN. However, the maximum phi(w) increased to 71%, 81%, and 77% for C-2-BCN, C-6-BCN, and C-12-BCN, respectively, 150 h after the initial emulsification, thereby creating high internal phase water-in-toluene emulsions. The observed time-dependent behavior of these emulsions is consistent with the disentanglement and dispersion of freeze-dried modified BCN bundles into individual nanofibers with time. These emulsions exhibited catastrophic phase separation when phi(w) was increased, as opposed to catastrophic phase inversion observed for other Pickering emulsions.
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