Conformations and Effective Interactions of Polymer-Coated Nanoparticles at Liquid Interfaces

We investigate conformations and effective interactions of polymer-coated nanoparticles adsorbed at a model liquidliquid interface via molecular dynamics simulations. The polymer shells strongly deform at the interface, with the shape governed by a balance between maximizing the decrease in interfacial area between the two solvent components, minimizing unfavorable contact between polymer and solvent, and maximizing the conformational entropy of the polymers. Using potential of mean force calculations, we compute the effective interaction between the nanoparticles at the liquidliquid interface. We find that it differs quantitatively from the bulk and is significantly affected by the length of the polymer chains and by the solvent quality. Under good solvent conditions, the effective interactions are always repulsive and soft for long chains. The repulsion range decreases as the solvent quality decreases. In particular, under poor solvent conditions, short chains may fail to induce steric repulsion, leading to a net attraction between the nanoparticles, whereas with long-enough chains the effective interaction potential may feature an additional repulsive shoulder at intermediate distances.