Journal
LANGMUIR
Volume 29, Issue 10, Pages 3446-3452Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la305045n
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Funding
- NSERC
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A star-shaped molecule with three butadiyne moieties attached to a central phenyl core was self-assembled via organogel formation in different solvents and subjected to UV irradiation in its xerogels form to give a soluble conjugated 1D nanowire made of three connected polydiacetylene (PDA) chains. The resulting polymer has a slightly lower optical band gap than its linear counterpart and presents no chromism property, indicative of the rigid nature of the polymer thus obtained.
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