4.6 Article

Membranes of Vertically Aligned Superlong Carbon Nanotubes

Journal

LANGMUIR
Volume 27, Issue 13, Pages 8437-8443

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la200995r

Keywords

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Funding

  1. NSF [CMMI-1047655]
  2. DOE [DE-SC0003736]
  3. AFOSR [FA9550-10-1-0546]
  4. AFOSR-MURI
  5. State Key Laboratory of Chemical Engineering [SKL-ChE-09D05]
  6. 111 Project [B07012]
  7. Directorate For Engineering
  8. Div Of Civil, Mechanical, & Manufact Inn [1047655] Funding Source: National Science Foundation

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In the present work, we have developed a simple but effective method to prepare superlong vertically aligned carbon nanotubes (SLVA-CNT) and epoxy composite membranes, and we have demonstrated that various liquids, including water, hexane, and dodecane, can effectively pass through the SLVA-CNT membranes. These results were confirmed by molecular dynamics simulations, While the mechanical densification was used to further enhance the flow transport through the SLVA-CNT membranes, we developed in this study a magnetic-nanoparticle switching system to turn on and off the flow through the nanotube membrane by simply applying an alternating voltage. The methodologies developed in this study should have a significant implication to the development of various smart membranes for advanced intelligent systems.

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