4.6 Article

Temperature and Solvent-Dependent Morphological Sol Gel Transformation: An in Situ microscopic observation

Journal

LANGMUIR
Volume 26, Issue 5, Pages 3106-3114

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la904264u

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Funding

  1. National Science Foundation of China [NSFC-20433060, NSFC-20743003, NSFC-20903074]
  2. Chanxueyan Cooperative Projects of Guangdong Province
  3. Ministry of Education [2007 B090400 076]
  4. Daoqum Chemical Enterprise Ltd

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A thermoreversible self-assemble process front gel (fiber) to sol (vesicle) state in the system alkylamine-ethylene glycol is for the first time monitored by in situ polarized optical microscopy, XRD, H-1 NMR, SEM, SAXRD, FTIR and drop shape analysis. It is found that the solvent molecules are intercalated with alkylamine molecule to form the organogel and Vesicle structures. A model based oil structural transformation with respect to these alkylamine gelator-solvent assembles is therefore proposed.

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