Journal
LANGMUIR
Volume 26, Issue 2, Pages 1117-1123Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la902108s
Keywords
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Funding
- AFOSR [FA9550-06-1-0526]
- DURI-AFRL [FA8650-06D-5401]
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Silver sulfide and cadmium sulfide nanoparticles of controllable sizes are synthesized using a water-in-hexane microemulsion method and stabilized by dodecanethiol. The stabilized metal sulfide nanoparticles can be deposited homogenously on flat substrates forming ordered 2-D arrays in supercritical fluid carbon dioxide (Sc-CO(2)). The use of Sc-CO(2) leaves the particles unaffected by dewetting effects Caused by traditional solvents and produces uniform arrays. The Sc-CO(2) deposition technique is capable of filling nanoparticles in nanostructures of silicon wafers which is difficult to accomplish by conventional solvent evaporation methods.
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