Journal
LANGMUIR
Volume 26, Issue 5, Pages 3388-3393Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la9031688
Keywords
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Funding
- Australian Research Council
- CSIRO OCE
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A brominated plasma polymer (BrPP) thin film was fabricated on a variety of substrate surfaces (silicon wafers, glass, gold, and polymers) via the radio frequency glow discharge of 1-bromopropane. This BrPP thin film was highly adherent and stable and was found to be a useful platform for secondary reactions, leading to surfaces with specific chemical functionalities. Following nucleophilic exchange, an azide-functionalized PP thin film was prepared that was reactive toward two different alkynes via the copper-catalyzed azide-alkyne cycloaddition (CuAAC) reaction, a paradigm of click chemistry. Click microcontact printing (mu CP) of a fluorescent alkyne was also successfully carried out. demonstrating the versatility and functionality of this new class of reactive thin film plasma polymer coatings.
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