Journal
LANGMUIR
Volume 26, Issue 10, Pages 6989-6994Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la904225k
Keywords
-
Funding
- Kodak and School of Chemistry at the University of Bristol
- EPSRC [EP/C523105/1, EP/F020686]
- Engineering and Physical Sciences Research Council [EP/C523105/1] Funding Source: researchfish
Ask authors/readers for more resources
Reversed-micelle synthesis has been used to generate CTAB-stabilized gold (Au-NPs) and silver nanoparticles (Ag-NPs). By inducing a phase transition and subsequent separation of the background supporting microemulsion, it has been possible to extract and purify the NPs front the reaction medium. After addition of excess water, the NPs concentrate into an upper octane-rich phase, with impurities and reaction debris (in particular CTAB) partitioning into the water-rich lower phase. UV and H-1 NMR showed that 82% of the original mass of Au-NPs can be purified from the excess CTAB and other salt impurities. The concentrated and purified NPs can be dried down, by solvent removal, and then redispersed in octane. Using the complementary techniques small-angle neutron and X-ray scattering (SANS and SAXS), the structures of microemulsions both with and without nanoparticles prior to separation, and in both upper and lower phases after separation, have been elucidated. The approach has also been applied to the synthesis and recovery of silver nanoparticles, but on a larger scale. This new approach compares favorably with existing methods as it uses no additional organic solvents, has a low-energy demand, and requires no specialist surfactants. The new advance here is that by using a colloidal system to prepare and support the nanoparticles as a structured solvent, a simple soft purification method becomes accessible, which is otherwise impossible with a normal molecular solvent.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available