Journal
LANGMUIR
Volume 25, Issue 14, Pages 8208-8216Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la900100w
Keywords
-
Funding
- MEC, Spain [MAT2005-07554-C02-01, MAT2008-06503/NAN, NAN2004-09133-C03-02, NAN2004-09195-C04-01, NAN2004-09203-C04-04, Nano-BioMed CONSOLIDER-INGENIO 2010]
- European Union [037465 - FLUOROMAG]
- EU-FP6 Framework Programme LIFESCIHEALTH-6
Ask authors/readers for more resources
We report evidence of the formation of small atomic copper clusters, Cu-n, by the microemulsion technique, and how their size can be controlled by adjusting the percentage of the reducing agent used. Copper clusters were characterized by UV-visible spectrophotometry and atomic force microscopy. Photoluminescent copper clusters, Cu-n, with n <= 13, can be obtained using very low percentages of the reducing agent (< 10% of the stochiometric amount). Photoluminescent clusters disappear for larger percentages of reducing agent, giving rise to larger copper clusters (0.8-2.0 nm), showing a red-shift of their UV-visible absorption bands as they grow in size. Finally, by using near stoichiometric amounts. nanoparticles of 2.9 +/- 1.1 nm in size, displaying the characteristic plasmon band, can be obtained.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available