Journal
LANGMUIR
Volume 25, Issue 22, Pages 13120-13124Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la901779k
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Funding
- NIEHS/NIH [ES013557]
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We have achieved reversible tunability of local surface plasmon resonance in conjugated polymer functionalized gold nanoparticles. This property was facilitated by the preparation of 3,4-ethylenedioxythiophene (EDOT) containing polynorbornene brushes on gold nanoparticles via surface-initiated ring-opening metathesis polymerization. Reversible tuning of the surface plasmon band was achieved by electrochemically switching the EDOT polymer between its reduced and oxidized states.
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