4.6 Article

Photochemical Formation of Silver Nanodecahedra: Structural Selection by the Excitation Wavelength

Journal

LANGMUIR
Volume 25, Issue 6, Pages 3802-3807

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la803814j

Keywords

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Funding

  1. National Natural Science Foundation of China [20773045, 20627002, 20573041]
  2. 111 project [1306009]
  3. National Institute of Justice [2006-DN-BX-K034]
  4. City University Collaborative Incentive program [80209]
  5. National Science Foundation [RII-9353488, CHE-0091362, CHE-0345987, ECS0217646]
  6. City University of New York PSC-BHE Faculty Research Award Program
  7. Direct For Education and Human Resources
  8. Division Of Human Resource Development [833180] Funding Source: National Science Foundation

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Silver decahedra have been successfully synthesized with high yield via a photochemical reaction using blue light-emitting diodes (LEDs) as the exciting light source. The decahedra display distinct properties with respect to the ability of light scattering. The photochemical growth process of silver decahedra was monitored by both extinction and scattering spectral evolution. A suggested formation mechanism of silver decahedron is discussed.

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