Journal
LANGMUIR
Volume 25, Issue 3, Pages 1713-1717Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la802995b
Keywords
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Funding
- National Science Foundation Committee of China [50873044]
- Program for New Century Excellent Talents in Universities of the China Ministry of Education
- Special Foundation for PhD Program in Universities of the China Ministry of Education [20050183057]
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A twin-tapered bi-1,3,4-oxadiazole derivative (BOXD-T8) showed a monomeric feature and intramolecular charge transition at concentrations lower than 10(-5) mol/L. BOXD-T8 molecules self-assembled to nanoparticles and further to helical nanofibers with blue fluorescence emission in DMSO, while nanoribbons resulted in an emission-enhanced gel in ethanol. The strong fluorescent emissions of BOXD-T8 in an isolated state in apolar solvents were attributed to the coplanar conformation of the rigid backbone and the strong fluorescent emissions of BOXD-T8 in the aggregation states were attributed to the coplanar conformation of the rigid backbone and J aggregation.
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