Journal
LANGMUIR
Volume 24, Issue 8, Pages 4231-4237Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la703662w
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An intramolecular charge-transfer (ICT) Compound, (TCBD)(2)OPV3, has been synthesized and fabricated into one-dimensional nanotubes by a reprecipitation method. The observation of SEM and TEM showed the nanotubes were formed from their zero-dimensional precursors of hollow nanospheres. Reconstruction was found to happen during the morphology transition progress. The morphology transition and reconstruction are proposed to be a curvature strain releasing process driven by donor-acceptor dipole-dipole interactions. An aggregation-induced emission (AIE) effect was observed for (TCBD)(2)OPV3. Both aggregates of vesicles and nanotubes were observed to be good red emitters with near-infrared end emission of 750-850 nm, which endows the material with potential applications in the fields of optical devices, biosensors, and biolabels.
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