4.6 Article

Rings of Nanoparticle-Decorated Honeycomb-Structured Polymeric Film: The Combination of Pickering Emulsions and Capillary Flow in the Breath Figures Method

Journal

LANGMUIR
Volume 24, Issue 20, Pages 11338-11341

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la8024217

Keywords

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Funding

  1. Natural Science Foundation of China [NSFC-20774082, 50830106]
  2. 863 National High-Tech RD Program [2006AA03Z329, 2006AA03Z444]
  3. Program for New Century Excellent Talents in University [NCET-05-0527]

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The self-assembly of nanoparticles at the fluid/fluid interface (Pickering emulsions) in the breath figures (BF) method have been explored to direct nanoparticles onto BF microarrays and adjust the BF assembly in microsize. Circular rings of nanoparticle-decorated honeycomb-structured polymeric film can be obtained by a one-step process. The combination of Pickering emulsions and capillary flow in the BF method may be responsible for the formation of this intriguing structure.

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