Journal
LANGMUIR
Volume 24, Issue 17, Pages 9223-9226Publisher
AMER CHEMICAL SOC
DOI: 10.1021/la801759d
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Funding
- U.S. Department of Energy [DE-FG02-00ER 14980]
- National Science Foundation [CHE-0743190]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0743190] Funding Source: National Science Foundation
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Minute stoichiometric bimetallic Clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogenation catalysts: these molecular metallic entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.
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