Enhancing the productivity of high-magnesium soil and water resources in Central Asia through the application of phosphogypsum

Recent evidences from some irrigated areas worldwide, such as Central Asia, suggest that water used for irrigation contains magnesium (Mg(2+)) at levels higher than calcium (Ca(2+)). Excess levels of Mg(2+) in irrigation water and/or in soil, in combination with sodium (Na(+)) or alone, result in soil degradation because of Mg(2+) effects on the soil's physical properties. More than 30 per cent of irrigated lands in Southern Kazakhstan having excess levels of Mg(2+) are characterized by low infiltration rates and hydraulic conductivities. The consequence has been a gradual decline in the yield of cotton (Gossypium hirsutum L.), which is commonly grown in the region. These soils require adequate quantities of Ca(2+) to mitigate the effects of excess Mg(2+). As a source of Ca(2+), phosphogypsum-a byproduct of the phosphorous fertilizer industry-is available in some parts of Central Asia. In participation with the local farming community, we carried out a 4-year field experiment in Southern Kazakhstan to evaluate the effects of soil application of phosphogypsum-0, 4.5, and 8.0 metric ton per hectare (t ha(-1))-on chemical changes in a soil containing excess levels of Mg(2+), and on cotton yield and economics. The canal water had Mg(2+) to Ca(2+) ratio ranging from 1.30 to 1.66 during irrigation period. The application of phosphogypsurn increased Ca(2+) concentration in the soil and triggered the replacement of excess Mg(2+) from the cation exchange complex. After hat-vesting the first crop, there was 18 per cent decrease in exchangeable magnesium percentage (EMP) of the surface 0.2 m soil over the pre-experiment EMP level in the plots where phosphogypsurn was applied at 4.5 t ha(-1), and a 31 per cent decrease in EMP in plots treated with phosphogypsum at 8 t ha(-1). Additional beneficial effect of the amendment was an increase in the soil phosphorus content. The 4-year average cotton yields were 2.6 t ha(-1) with 8 t ha(-1) phosphogypsum, 2.4 t ha(-1) with 4.5 t ha(-1) phosphogypsum, and 1.4 t ha(-1) with the control. Since the amendment was applied once at the beginning, exchangeable Mg(2+) levels tended to increase 4 years after its application, particularly in the treatment with 4.5 t ha(-1) phosphogypsum. Thus, there would be a need for phosphogypsurn application to such soils after every 4-5 years to optimize the ionic balance and sustain higher levels of cotton production. The economic benefits from the phosphogypsurn treatments were almost twice those from the control. Copyright (c) 2007 John Wiley & Sons, Ltd.