Journal
PURE AND APPLIED CHEMISTRY
Volume 87, Issue 11-12, Pages 1139-1150Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2014-0502
Keywords
aqueous solutions; chemical equilibrium; chemical thermodynamics; inorganic chemistry; IUPAC Physical and Biophysical Chemistry Division; oxidation; radicals; standard electrode potentials
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Funding
- IUPAC
- ETH ETH Stiftung
- US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences [DE-AC02-06CH11357, DE-AC02-98CH10886]
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Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pK(a)'s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
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