4.4 Article

Fabrication and modification of polyvinylchloride based heterogeneous cation exchange membranes by simultaneously using Fe-Ni oxide nanoparticles and Ag nanolayer: Physico-chemical and antibacterial characteristics

Journal

KOREAN JOURNAL OF CHEMICAL ENGINEERING
Volume 30, Issue 6, Pages 1265-1271

Publisher

KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-013-0063-2

Keywords

Cation Exchange Membrane; Fabrication/Modification; Ag Nanolayer/Fe-Ni Oxide Nanoparticles; Physico Chemical/Antibacterial Characteristic; Synergy Phenomenon

Funding

  1. Arak University
  2. Iran Nanotechnology Initiative Council

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Polyvinylchloride-blend-styrene butadiene rubber based nanocomposite cation exchange membranes were prepared by solution casting technique. Iron-oxide nanoparticles and Ag-nanolayer were simultaneously utilized as filler and surface modifier in membrane fabrication. The effects of Ag-nanolayer film thickness on membrane physicochemical and antibacterial characteristics of nanocomposite PVC-blend-SBR/Iron-oxide nanoparticles were studied. SEM images showed membrane roughness decreasing by Ag nanolayer thickness increasing. Membrane charge density and selectivity declined by Ag nanolayer coating up to 5 nm in membranes and then showed increasing trend by more nanolayer thickness. Ionic flux also showed increasing trend. Membranes showed good ability in E-Coli removal. 20 nm Ag-nanolayer coated membrane showed better performance compared to others.

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