Journal
KINETICS AND CATALYSIS
Volume 55, Issue 2, Pages 148-153Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0023158414020153
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Extracts from tissues of the holothuria Eupentacta fraudatrix suppress the oxy-chemiluminescence of ethylbenzene in chlorobenzene initiated by azobisisobutyronitrile thermolysis and enhanced by energy transfer to 9,10-dibromoanthracene. The decrease of the chemiexcitation rate in the reaction between peroxyl radicals is caused by radical interception by the antioxidants contained in the extracts. The concentrations of the antioxidants in the extracts and the rate constants of their reactions with peroxyl radicals have been estimated from chemiluminescence kinetics.
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