4.8 Article

Lightweight Raman spectroscope using time-correlated photon-counting detection

Publisher

NATL ACAD SCIENCES
DOI: 10.1073/pnas.1516249112

Keywords

Raman spectroscopy; lightweight spectrometer; time-correlated single-photon counting; remote sensing; environmental sensing

Funding

  1. National Science Foundation [PHY-1241032, CBET-1250363, DBI-1455671, DBI-1532188]
  2. ECCS [1509268]
  3. NIH [R21-EB011703, R01-HL11136, R01-CA138653]
  4. Robert A. Welch Foundation [A-1261]
  5. Directorate For Engineering
  6. Div Of Chem, Bioeng, Env, & Transp Sys [1250363] Funding Source: National Science Foundation
  7. Div Of Biological Infrastructure
  8. Direct For Biological Sciences [1455671] Funding Source: National Science Foundation
  9. Div Of Electrical, Commun & Cyber Sys
  10. Directorate For Engineering [1509268] Funding Source: National Science Foundation

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Raman spectroscopy is an important tool in understanding chemical components of various materials. However, the excessive weight and energy consumption of a conventional CCD-based Raman spectrometer forbids its applications under extreme conditions, including unmanned aircraft vehicles (UAVs) and Mars/Moon rovers. In this article, we present a highly sensitive, shot-noise-limited, and ruggedized Raman signal acquisition using a time-correlated photon-counting system. Compared with conventional Raman spectrometers, over 95% weight, 65% energy consumption, and 70% cost could be removed through this design. This technique allows space- and UAV-based Raman spectrometers to robustly perform hyperspectral Raman acquisitions without excessive energy consumption.

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