Journal
APPLIED PHYSICS LETTERS
Volume 106, Issue 11, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4916079
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Funding
- National Science Foundation [NSF CBET-1437656, DMR-1303742]
- National Natural Science Foundation of China [51203192, 51173205, 11334014]
- Natural Science Foundation of Hunan Province, China [12JJ3003]
- U.S. Department of Energy [DE-EE0006709]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1437656] Funding Source: National Science Foundation
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The thickness dependence of fullerene on CH3NH3PbI3 perovskite film surface has been investigated by using ultraviolet photoemission spectroscopy (UPS), X-ray photoemission spectroscopy (XPS), and inverse photoemission spectroscopy (IPES). The lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) can be observed directly with IPES and UPS. It is observed that the HOMO level in fullerene shifts to lower binding energy. The XPS results show a strong initial shift of core levels to lower binding energy in the perovskite, which indicates that electrons transfer from the perovskite film to fullerene molecules. Further deposition of fullerene forms C-60 solid, accompanied by the reduction of the electron transfer. The strongest electron transfer happened at 1/4 monolayer of fullerene. (C) 2015 AIP Publishing LLC.
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