4.7 Article

The relationship between properties of fluorinated graphite intercalates and matrix composition 7

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 117, Issue 1, Pages 235-241

Publisher

SPRINGER
DOI: 10.1007/s10973-014-3635-4

Keywords

Inclusion compounds; Intercalates; Fluorinated graphite; Isothermal kinetics; Thermal stability

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Inclusion compounds (intercalates) of fluorinated graphite matrix with ethyl acetate (C2FxBrz center dot yCH(3)COOC(2)H(5), x = 0.49, 0.69, 0.87, 0.92, z = 0.01) were prepared by guest substitution from acetonitrile to ethyl acetate. The kinetics of the thermal decomposition (the first stage of filling -> the second stage of filling) was studied under isothermal conditions at 291-307 K. The relationship of the host matrices' structure with inclusion compounds' thermal properties and kinetic parameters is discussed.

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