Fast co-pyrolysis of coal and biomass in a fluidized-bed reactor

Co-pyrolysis is one of the most promising options for the utilization of coal and biomass. Coal/biomass blends were prepared using Yilan subbituminous (YL) and corncob and the mass ratios of coal in mixtures varied between 0 and 100 %. Co-pyrolysis characteristics were investigated in a thermogravimetric analyzer from 303 to 973 K under the nitrogen flow of 100 mL min(-1). The co-pyrolysis residues were less than the sum simply added of the solid yields of individuals. With heating rate increased from 10 to 40 K min(-1), the residues decreased more severely compared to the expected under various blending ratios. For fast pyrolysis in fluidized-bed reactor, gas volumes and char yields of co-pyrolysis showed a significant linearity. But pyrolysis-oil yields were higher than the expected from the additive model when the YL blending ratios were less than 60 %. The co-pyrolysis evolved more H-2, CH4, C-2 + C-3, and less CO than an additive pyrolysis process of individual fuel. The GC/MS results indicated that co-pyrolysis-oil contained more alcohols, ketones, aldehydes, or acids than that of individual fuel. All of that suggested the H/OH in volatiles produced from rapid pyrolysis of biomass transferred to the radicals of coal pyrolysis. The possible reaction mechanism also was provided in the paper.