4.7 Article

Thermochemical characterization of chicken litter and peat as a source for energy recovery

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 113, Issue 2, Pages 683-692

Publisher

SPRINGER
DOI: 10.1007/s10973-012-2771-y

Keywords

Poultry waste; Chicken litter; Peat; Soil conditioning; Bio-energy; Ecology

Funding

  1. Bulgarian National Scientific Research Fund [DRNF02/10, DRNF02/01, DNTS/Slovakia/01/3]
  2. European Territorial Cooperation'' Operational Programme Greece, Bulgaria [B1.11.02/14.03.2011]

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The shortage of raw materials and the environmental problems due to pollution require development of new green technologies utilizing some wastes and transforming them to secondary raw materials. The aim of this work is to study the properties of poultry waste to propose possibilities to minimizing the released emissions and avoiding the risk for human health and the environment. At the same time, two types of low grade peats with different origin are studied as components for the production of soil conditioners. During the studies, we applied the inductively coupled plasma (ICP) and chemical analysis, powder X-ray diffraction, thermal analysis, IR spectroscopy, and scanning electron microscopy for determining the composition, crystal phase, the shape and size of particles, and thermal stability of the investigated samples. The chemical and the phase compositions of the studied samples confirmed that the content of nutrient compounds and of the carbon substances is suitable as an effective secondary raw material for soil conditioners. It is found that the poultry wastes and peat samples have a similar phase and chemical composition and contain an organic mass in the form of carbon components with amorphous, fibrous, and skeleton-like structure, suitable to be combined with other nutrient-containing compounds. During the thermal treatment, the carbon compounds are oxidized releasing heat. Based on that the materials under study are considered as environmentally friendly fuels, releasing relatively low emissions.

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