Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 102, Issue 2, Pages 517-521Publisher
SPRINGER
DOI: 10.1007/s10973-010-0945-z
Keywords
Phospholane stability; Radical initiators; Phosphorus flame retardants; Five-membered heterocycles
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Certain five-membered dioxaheterocyclic compounds (hetero atoms may be P, Si, S, etc.) contain a strained carbon-carbon bond which may undergo homolytic thermolysis at modest temperatures to generate a diradical capable of initiating vinyl polymerization. If substituents contain flame-retarding moieties this represents a convenient method for imparting flame retrdancy to a polymeric material. Of particular interest has been 2,4,4,5,5-pentaphenyl-1,3,2-dioxaphospholane. The thermal degradation of this compound has been studied using (13)C NMR spectroscopy. This may conveniently be done by monitoring the intensity of the signal for the benzylic carbon atom as a function of time and temperature. A simple transformation is the conversion of the cyclic compound to the linear polymer.
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