Journal
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
Volume 78, Issue 11, Pages 1809-1836Publisher
SERBIAN CHEMICAL SOC
DOI: 10.2298/JSC130809097J
Keywords
polymer; oligomer; oxidative polymerization; arylamine; polyaniline; nanostructure
Categories
Funding
- Ministry of Education, Science and Technological Development of the Republic of Serbia [OI 172043]
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Recent advances in synthesis, characterization and application of the selected conducting/semiconducting and redox-active oligomers and polymers of arylamines are reviewed. A brief historical background of the selected topics is given. The overview of the preparation, structure and properties of polyaniline, substituted polyanilines, especially those obtained by the oxidative polymerization of p-substituted anilines, poly(1-aminonaphthalene) and its derivatives, carbocyclic and heterocyclic polyaryldiamines such as poly(p-phenylenediamine) and polydiaminoacridines, is presented. The mechanism of formation of polyaniline nanostructures is discussed. Recent approaches to the preparation of one-dimensional polyaniline nanostructures are concisely reviewed, with special attention paid to the template-free falling-pH method. Current and potential future applications of oligo/polyarylamines are briefly discussed.
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