Journal
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
Volume 77, Issue 8, Pages -Publisher
PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.77.083802
Keywords
chirality; crystallization; enantiomer; dynamical symmetry breaking; chiral cluster; autocatalysis; NaClO3; amino acid derivative
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By grinding crystals in a solution, the chirality conversion of the crystal structure and the resultant conversion Of Molecular chirality have been realized recently. Reaction-type models that enable (lie reproduction of these phenomena are Studied. In the models, chiral clusters are assumed to be formed by grinding and that these clusters can be integrated into crystals of the same chirality. An initial chirality imbalance is amplified exponentially, and the rate is approximately proportional to the grinding strength and to the molecular racemization rate in a relevant parameter range.
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