4.4 Article

Spectroscopic study of Cr4+-doped transparent willemite nanocrystalline glass-ceramics

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OPTICAL SOC AMER
DOI: 10.1364/JOSAB.27.001659

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  1. National Natural Science Foundation of China (NSFC) [60508014, 50772102]
  2. New Century Excellent Talents in University [NCET-07-0786]
  3. Nature Science Foundation of Zhejiang Province [R406007, Y4080268]

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Cr4+-doped transparent beta-Zn2SiO4 glass-ceramics were prepared by heat treatment on the as-made glasses. It was confirmed from the absorption spectra that Cr4+-doped beta-Zn2SiO4 glass-ceramics are indeed a low-field system. The broadband infrared emission centering at 1342 nm with the full width at half-maximum of more than 285 nm was observed by exciting the glass-ceramics with the excitation of an 808 nm laser diode. The observed infrared emission could be attributed to Cr4+ ions at low-field sites in beta-Zn2SiO4 glass-ceramics. (C) 2010 Optical Society of America

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