Journal
APPLIED PHYSICS LETTERS
Volume 107, Issue 2, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.4926648
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Funding
- Ministry of Science and Technology, Taiwan [NSC 102-2221-E-007-0418-MY3]
- National Tsing Hua University [102N2701E1]
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Effect of twin boundary (TB) spacing on atomic surface structure and chemical reactivity of nanotwinned Cu nanowires (NWs) is investigated. Post-etching surface structure and wire diameter of Cu NWs were examined by transmission electron microscopy. When TB spacing is less than 10 nm, the Cu NWs remain almost intact after chemical attack and show faceted surface structures with low atomic step density. A mechanism based on surface tension torque acting on TB/surface triple junctions is proposed to explain the faceted structure formation and enhanced corrosion resistance of nanotwinned Cu NWs. (C) 2015 AIP Publishing LLC.
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