Modeling viscoelastic dielectrics

Dielectric elastomers, as an important category of electroactive polymers, are known to have viscoelastic properties that strongly affect their dynamic performance and limit their applications. Very few models accounting for the effects of both electrostatics and viscoelasticity exist in the literature, and even fewer are capable of making reliable predictions under general loads and constraints. Based on the principles of non-equilibrium thermodynamics, this paper develops a field theory that fully couples the large inelastic deformations and electric fields in deformable dielectrics. Our theory recovers existing models of elastic dielectrics in the equilibrium limit. The mechanism of instantaneous instability, which corresponds to the pull-in instability often observed on dielectric elastomers, is studied in a general non-equilibrium state. The current theoretical framework is able to adopt most finite-deformation constitutive relations and evolution laws of viscoelastic solids. As an example, a specific material model is selected and applied to the uniform deformation of a dielectric elastomer. This model predicts the stability criteria of viscoelastic dielectrics and its dependence on loading rate, pre-stress, and relaxation. The dynamic response, as well as the hysteresis behavior of a viscoelastic dielectric elastomer under cyclic electric fields, is also studied. (C) 2010 Elsevier Ltd. All rights reserved.