Journal
JOURNAL OF THE KOREAN PHYSICAL SOCIETY
Volume 55, Issue 1, Pages 212-216Publisher
KOREAN PHYSICAL SOC
DOI: 10.3938/jkps.55.212
Keywords
TMTSF; Organic semiconductor; Parylene; Polymer; Pentacene; OFET
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The free-standing single crystal tetramethyltetraselenafulvalene (TMTSF) has been grown with physical vapor deposition (PVD) technique. X-ray diffraction (XRD) analysis shows that both the metallic (TMTSF)(2)PF6 and the semiconducting TMTSF have a triclinic crystal structure with a P-1 space group. The TMTSF single crystal forms a brick wall like stacking structure within the ac-plane, which reduces the overall anisotropy of the system. The intrinsic electrical transport properties of the semiconducting TMTSF were probed, utilizing a polymer-based field effect transistor. The TMTSF organic semiconductor exhibited a typical p-type semiconducting characteristics. The field effect mobility was obtained as 3.96 cm(2)/Vs. which is an order of magnitude higher than the value reported previously for single crystal TMTSF.
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