Journal
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
Volume 8, Issue 2, Pages 545-552Publisher
SPRINGER
DOI: 10.1007/BF03249089
Keywords
2-Amino-5-oxo-4,5-dihydropyrano[3,2-c]chromene-3-carbonitrile; Ionic liquid; Multi-component reaction; Catalysis
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A new ionic liquid, 3-hydroxypropanaminium acetate (HPAA) [H3N+-CH2-CH2-CH2-OH][CH3COO-], was synthesized for the first time and used as an efficient and recoverable catalyst in the synthesis of 2-amino-5-oxo-4,5-dihydropyrano[3,2-c]chromene-3-carbonitrile derivatives by condensing together 4-hydroxycoumarin, aldehydes and malononitrile at room temperature. The catalyst can be reused for four times without noticeable loss of activity.
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