Journal
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
Volume 8, Issue 4, Pages 1006-1013Publisher
SPRINGER
DOI: 10.1007/BF03246556
Keywords
gem-Dihydroperoxides; Aluminium chloride hexahydrate; AlCl3 center dot 6H(2)O; Ketones; Aldehydes; Aqueous H2O2
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Funding
- Research Council of Bu-Ali Sina University, Hamedan, Iran
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AlCl3 center dot 6H(2)O was explored as an efficient catalyst for the synthesis of gem-dihydroperoxides (DHPs) from ketones and aldehydes. The reactions took place within a short period of time using (30%) aqueous H2O2 as a green oxidant in acetonitrile under neutral conditions at room temperature to afford the products in high yields.
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